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Recent results have supplied new insights into riboswitch folding energy landscapes, the mechanisms of ligand binding, the roles played by divalent ions, the applicability of hierarchical folding models, and kinetic vs. thermodynamic control schemes.
Impact of important closure models such as drag models, viscous stress models, boundary conditions, droplet vaporization models, and kinetic models on predictions is critically examined.
In order to improve the reliability of models and kinetic parameter values, a stepwise strategy that combines batch and continuous flow tests with adequate true-to-the mechanism analytical of numerical models, and decouples the kinetics of purely reactive steps of sorption from physical mass-transfer processes is required.
In a biosorption study, it is necessary to fit the equilibrium biosorption data using different biosorption isotherm models and kinetic equations in order to analyze and design a biosorption process.
The equilibrium and kinetic data of metal ions adsorption were analyzed using Langmuir and Freundlich adsorption models and kinetic models: pseudo first order, pseudo second order, intraparticle kinetic model, and Elovich.
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The combination of turbulence sub-models, fluence rate sub-models, and kinetic rate equations resulted in a comprehensive and flexible design tool for predicting the effluent chemical composition from a UV-initiated AOP reactor.
Kinetic modelling and kinetic parameter estimation based on experimental kinetic data were included.
Additionally, an adsorption model and kinetic are discussed in this paper.
A reactor radiation reaction model was developed, which was comprised of the reactor mass balance, radiation model, and kinetic model for the degradation of formic acid.
Isotherm modeling and kinetic investigations showed that Langmuir, modified Langmuir, and pseudo-second-order models describe both the adsorption equilibrium and kinetic behavior well.
Modeling was based on a 1-D premixed flame model and kinetic mechanisms available in the literature.
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