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Our purpose, besides exploring these particular model reactions, is to understand how the mechanism of bond activation changes as the catalytically active species changes from a simple, uncoordinated metal atom to a metal ligand coordination complex.
Direct comparison of model reactions is hampered by the fact that different models use different conventions for naming metabolites and writing reactions.
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Transient simulations of six model reactions are carried out.
Model reactions were carried out before the synthesis of the functionalized polymers.
To find a method to enhance the toughness of neat SA9000 thermoset, three model reactions are designed.
The CO + NO and CO + NO + O2 model reactions were studied over fresh and aged catalysts.
The model reactions are adsorption-desorption types with Eley-Rideal surface kinetics.
Typical model reactions are: Eley Rideal mechanism, Langmuir Hinshelwood mechanism, monomolecular decomposition and catalyst poisoning.
The model reactions were carried out to investigate varies solvents, bases, catalytic systems and substrate reactivity effects on the Ullmann CN coupling reactions.
Model reactions were carried out with components frequently used for the preparation of intercalated or exfoliated polypropylene (PP) nanocomposites.
Two model reactions were selected: the catalyzed photooxidation of 4-chlorophenol (4-CP) and the singlet oxygen chemical quencher 9,10-dimethylanthracene (DMA) in dimethylformamide.
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CEO of Professional Science Editing for Scientists @ prosciediting.com