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Also, the effect of the catalyst load on the model reaction was studied.

Meanwhile, the model reaction was studied with 10 mol % of SnO2 NPs under various temperatures.

To study the catalyst reusability, the model reaction was carried out using 0.015 g of Fe3O4/camphor.

Accordingly, a model reaction was performed by using PNC4.0 as the photo-catalyst with a definite amount of reactants for 50 h.

The selected model reaction was performed over a 4 wt.% palladium/alumina catalyst using 30% (v/v) isopropanol/water solvent.

In the present study, the enzymatic esterification of dihydrocaffeic acid (DHCA) with 1- hexanol (Fig. 1) as a model reaction was carried out in ionic liquid [1-butyl-3-methylimidazoliumbis (trifluoromethylsulfonyl) imide].

With the assumed chemical model, reaction is confined to a thin reaction zone.

One of the reasons to use the 4-NP to 4-AP reduction reaction as a model reaction is that the reaction progress can be followed directly by UV-visible spectrophotometry.

The model reaction is chosen to allow investigation of the position of chemical reactions (gas phase, surface, liquid phase) and the behavior of typical products (alcohols and aldehydes).

The reactants, products, intermediates (Im), and transition-state (TS) geometries in the model reaction were optimized using the DFT/B3LYP method implemented in the Gaussian 09 package.

The relative free energies for all the species considered in various pathways of the model reaction are given in Table 1.