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The as-prepared hierarchical structured membranes (PDA@PDMS) were used to selectively collect hydrocarbons from nitrogen (propylene/nitrogen as a model gas pair) with considerably enhanced separation selectivity and high gas permeance.
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In addition, the data for the aged film of PIM-EA-TB crosses the 2008 upper bound for CO2/CH4 and is comparable with the data of the best performing PIMs for this commercially important gas pair.[ 11a] According to the solution-diffusion model the permeability of a gas through a dense polymer is dependent on both its diffusivity (D x) and its solubility (S x) (i.e., P x = D xS x).
A mean transport-pore model (MTPM) is proposed which requires permeation, steady-state diffusion or pulse chromatographic measurements with several gases or gas pairs and/or at different pressures and temperatures.
The separation mechanism of the gas pairs is also discussed.
Breakthrough performance of the four target gas pairs was characterized in a packed bed configuration using binary gas mixtures of the four target gas pairs.
Four different pore diffusion models are fitted to isobaric counter-diffusion fluxes measured in technical catalysts by a Wicke-Kallenbach cell over a 30-fold pressure range with different gas pairs.
Resultant CMS fiber showed interesting separation performance for several gas pairs, especially high selectivity for C2H4/C2H6.
Fig. 9 Robeson diagrams of the gas pairs: a H2/N2, b CO2/CH4, c O2/N2, and d CO2/N2.
Figure 15 Selectivity of different gas pairs as a function of PP-MWCNTs loading.
Analogically, selectivity increase for the gas pairs H2/N2 and H2/O2 are similar (50 %; 49 %).
For different gas pairs, the selectivity values are scattered around the Knudsen selectivity regime.
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