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As model compounds the emerging contaminants (ECs): desethylatrazine, sulfamethoxazole, carbamazepine, diclofenac, benzotriazole, tolyltriazole, iopamidole and 17α-ethinylestradiol (EE2) were degraded at initial compound concentrations of 1 μg/L in tap water and matrixes with increased organic load (46 mg/L DOC).
In most of the model compounds, the NMR method delivers hydrogen close to its theoretical values.
For 3-site and 4-site model compounds, the spin-correlation was found to be strongly dependent on the oxidation number and the molecular structure.
In order to study their structure-active relationship, we choose a highly active compound 4k and low activity compound 4c as model compounds; the frontier orbitals and LogP were calculated.
The results indicate that comparable asymmetric induction is found in polymers and model compounds, the former systems not exhibiting appreciable evidence of ordered secondary structures, in agreement with a low degree of stereoregularity along the macromolecular backbone.
From the activity tests using model compounds, the HDS activity of the fresh catalyst was found to increase up to 4.0 Mo atoms nm−2 with increasing CoMo loading.
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For the unprotected phenolic model compound the production of phenolic fragments is higher than in the labile substituted α-O-4 model compound.
This paper describes the use of FS on a sodium ion conductor based on a model compound, the beta-alumina.
By employing tin niobate as a model compound, the effects of phase structure over electronic structure, photocatalytic activity toward methyl orange solution and hydrogen evolution were systematically investigated.
Depending on the model compound, the characteristic structure of the TiO2/SBA-15 mallowsls allows increasing up to eight times the activity achieved by the Degussa P25 TiO2.
To simplify the kinetics and conduct studies with the most biologically relevant nerve agent model compound, the SP enantiomers were used.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com