Sentence examples for model compound scheme from inspiring English sources

To simplify the DFT calculations, dimethyl-aminomethyl furan (R-Model) was used as the model compound (Scheme 1).

In order to exclude conformational complications (e.g., the fluorohydrin gauche effect), 18, 19 this study was carried out using conformationally restricted model compounds 1– 8 (Scheme 1), which adopt only chair conformations as confirmed by computational analysis (see below).

Novel synthetic schemes to prepare supported forms of insoluble cesium- and ammonium-acid salts are discussed, and their behavior in model compound isomerization and alkylation reactions is described.

For experimental evaluation of EET, we first constructed model compound 10, in which eight coumarin moieties are attached directly to the peripheral carboxyl groups on the porphyrin via short ethylenediamine linkers (Scheme S1 of the Supporting Information).

The mechanism in Scheme 4 is supported by the kinetic isotope effects and the experiments with deuterium-labeled compounds (Scheme 2 and Scheme 3).

A dihydroxybenzyl-based group (192) was also developed for the protection of carbonyl compounds (Scheme 81).

Fig. 3 Model Development Scheme.

Thus, for example, reaction of dienyne 81 leads stereoselectively to tetracyclic compound 82 (Scheme 27).

Furthermore, esterification of the previously prepared compounds (14 22) afforded compounds (23 31) (Scheme 3).

Australia is the model for the scheme.

Figure 1 describes a schematic of compound synchronization scheme.