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Electrocatalytic activity of a new catalyst toward the oxidation reaction of hydroquinone as a model compound is described.
The aromatic geometry of EDOT TP model compound is transformed to quinoid in the corresponding copolymer and results in a small band gap (Eg) of 0.97 eV.
As an example for the application of this kind of bifunctional ligand systems, a [FeFe]-hydrogenase enzyme model compound is prepared and structurally characterized.
The spectrum of the model compound is the average of 2 scans.
Radical cations of acids 4 had not previously been characterised by EPR spectroscopy, but the g-factor and hfs were very similar to those reported for the radical cations of dimethoxybenzene.[ 67– 70] The aromatic core of this model compound is similar to that of acid 4 d.
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Polyurea/clay nanocomposite microcapsules containing dimethyl phthalate (DMP) as a model compound were prepared by interfacial polymerization technique.
This model compound was found to reduce methyl benzoylformate stereoselectively in good yield with 48% enantiomeric excess.
Benzyl phenyl ether (BPE), the lignin model compound, was treated at temperatures ranging from 220 to 250 °C.
In this work the deoxygenation of m-cresol, used as a bio-oil model compound, was studied at atmospheric pressure, using Pt/γ-Al2O3 catalysts.
Catalytic testing using birchwood xylan as a model compound was performed in batch reactors (working volume 12 mL, 16 wt% catalyst) over a range of temperatures (90 120°CC).
A hydroxy-containing imide model compound was also found to undergo thermal conversion to a bisbenzoxazole when heated above 400°C under nitrogen.
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