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Backscattered electron (BSE) images were acquired using a Hitachi S-3400 N-II in high vacuum mode, equipped with an Oxford INCAx-act SDD energy-dispersive spectrometer.

For Raman spectroscopy, a Horiba Jobin Yvon spectrometer in triple subtractive mode equipped with a liquid nitrogen-cooled CCD detector, 1800 gr/mm gratings, and a laser wavelength of 532 nm was used.

Samples eluted from SPE plates were analyzed using MALDI-ToF mass spectrometry (Autoflex II, ToF/ToF, Bruker Daltonics, Bremen, Germany) in linear-positive mode equipped with a 337 nm nitrogen laser and 2 GHz digitizer.

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MALDI-TOF MS/MS analysis was performed on a 4800 Proteomics Analyzer mass spectrometer (Applied Biosystems) in positive ion mode equipped with TOF/TOF optics and a 200 Hz NdYag laser.

NTEGRA spectra (AFM-Raman Spectrometer, NT-MDT, Russia) equipped with a liquid nitrogen-cooled CCD detector and an inverted optical microscope (Olympus IX71) were used to evaluate the pharmacology of Au-nanodots/ITO, RGD-peptide/Au-nanodots/ITO and cells using AFM using a semi-contact mode equipped with an inverted optical microscope under liquid conditions.

Transmission electron microscopy (TEM) has been performed with a FEI Tecnai F20ST, operating at 200 KV both in TEM and HRTEM modes, equipped with an EDAX Energy dispersive X-ray detector.

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The HPLC was coupled to an Agilent 6490 TripleQuad mass spectrometer (QqQ-MS) used in negative electrospray-ionization (ESI) mode and equipped with Agilent Jetstream technology.

The Co-2 × 2 nanoislands were fabricated in situ with the use of an Omicron VT-STM (Omicron Taiwan R. O. C. Office Omega Scientific Taiwan Limited, Taipei, Taiwan, Republic of China) (base pressure approximately 2 × 10-10 mbar) operating in constant-current mode and equipped with well-collimated evaporators for Ag and Co deposition.