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Overall oxygen solubility was associated with the solubility of mobile and rigid amorphous fractions.

Measurements of crystallinity and jump in the heat capacity at Tg were used to determine the amount of mobile and rigid amorphous fractions.

The ratio between mobile and rigid amorphous fractions increases with increasing crystallinity, suggesting increasing decoupling of crystals and amorphous phase in samples of high crystallinity, and confirming results obtained earlier on poly ethylene terephthalate) and isotactic polypropylene.

Thus, mobile and rigid residues can be distinguished and even spectroscopically "filtered out".

Both mobile and rigid alkyl chain components (30 and 33 ppm, respectively) appear in wild-type as well as in all of the genetically modified periderms, most prominently in the CYP86A33-RNAi periderm for which lamellar structure is absent.

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The development of the crystalline, mobile amorphous, and rigid amorphous fractions was analyzed as a function of thermal history, upon isothermal and non-isothermal crystallization.

Using quasi-isothermal (QI) heat capacity measurements, we investigate the formation behavior of the crystalline, mobile amorphous, and rigid amorphous fractions in poly trimethylene terephthalate), PTT.

The fractions of the crystal, mobile amorphous, and rigid amorphous phases of the non-woven, nanofibrous composite mats were quantified by using heat capacity measurements.

From the analysis of these experiments we conclude on the volumetric properties of the mobile (MAF) and rigid amorphous fractions (RAF) in these semicrystalline polymers.

A preliminary determination of the percentage of the different phases in the semi-crystalline samples (crystalline, mobile amorphous and rigid amorphous fractions) has been performed.

In this work, a three-phase model consisting of crystalline, mobile amorphous and rigid amorphous phases (RAP) was used to describe the structural formation of poly trimethylene terephthalate) (PTT) at various crystallization conditions.

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