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The NW shows a metallic conduction with a resistivity of only 2.5 larger than the Mo bulk resistivity.
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Reduction accommodated through the stabilization of bulk Mo sub-oxide phases is detrimental in terms of exchangeability of oxygen atoms.
In addition to this diffusion process, the formation of a deep tail of nitrogen into the bulk Mo was observed, starting near a temperature of approximately 500 °C.
The cohesive energies of the corresponding bulk Mo and W are 6.19 eV [29] and 8.54 eV [29] Figure 4 Activation energy of diffusion versus the size of the nanostructure for iron (Fe) and copper (Cu).
Individual nanowalls have a typical thickness of about 50 nm and very good conductivity with a typical average value of about 1.97 × 104 Ω−1 cm−1, i.e., only an order of magnitude less than the value of bulk Mo.
XRD and Raman spectroscopy reveal the presence of many Mo-phases, such as dispersed surface molybdenum specie, bulk MoO3 and Al2(MoO4)3 in the samples.
This results in hybridized Mo4d-S3p interandions and provides the covalent component of the Mo-S bonds in bulk MoS2.
The reference levels of calculated chemical potentials are bulk (D2) for Mo (S) dopants or defects.
The residual Mo congregated into 25 60 nm bulk clusters of α-Mo2C.
Mo species migrate from the bulk to the catalyst surface to compensate the Mo loss favoured by water.
Promising perovskites contain Co or Mn at the surface and Co doped with Mo or W in the bulk, such as CaCoO3-terminated La0.5Ca0.5Mo0.5Co0.5O3, SrCoO3-terminated Sr0.5La0.5Co0.5W0.5O3, and CaMnO3-terminated Sr0.5Ca0.5MnO3.
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