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The mixture of starting materials in stoichiometry was ball milled for 20 h and sintered into disks in a sealed crucible at 1100 °C for 3 h.
The evaporative loss of CsCl during glass melting was measured by energy-dispersive X-ray spectroscopy and corrected for by biasing the CsCl concentration in the mixture of starting materials to obtain glasses with accurately controlled stoichiometry.
Solid-state method is the most common method in which stoichiometric mixture of starting materials is ground or ball-milled together and the resultant mixture is heat-treated in a furnace [20, 21].
The low yield of 6 (~12%) was attributed to the monometalation process, giving a mixture of starting bis(free base) porphyrin 4, the desired monozinc complex 5, and dizinc complex.
Fung reported the synthesis of 5 and 6-carboxytetraethylrhodamine N-hydroxysuccinimide esters using N, N ′-disuccinimidyl carbonate (DSC) and DMAP, but in our hands, this gave a mixture of starting material and the di-ester product (Fig. 1).
The mixture of starting 4,4,6-trimethyl-1,2-dioxo-1,2-dihydro-4 H-pyrrolo[3,2,1 ij]quinolin-8-yl-3-[3,4-bis methyloxy phenyl]prop-2-enoate (0.433 g, 1 mmol) and rhodanij]quinolin-8-yl-3-[3,4-bis methyloxy phenyl]prop-2-enoates.
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For Kinkladze, the start of the 2001 02 season followed a similar pattern to the previous season, comprising a mixture of starts and substitute appearances.
Topher may not ever be a truly sympathetic character, but this mixture of suddenly starting to tell right from wrong and his growing sense that he's losing control of his creations brings us closer to understanding how he might move from season one's sarcastic cold-hearted science wonk to being the closed-off headcase we saw in epitaph one.
An equimolar mixture of the starting materials was mixed and compacted into a pellet.
A mixture of the starting material 2 (6.86 g, 0.01 mol)., appropriate aldehydes (0.01 mol).
More meaningfully, it achieves homogeneous mixture of the starting components, a low synthesis temperature and small grain size of the powders.
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