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Mixtures showed exothermic mixing; excess molar enthalpies exhibited a minimum in the CO2-rich region.
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Mixtures formed by low-density carbon dioxide and linalool show very exothermic mixing and excess molar enthalpies exhibit a minimum in the CO2-rich region.
In most cases, CO2 + DMF mixtures showed very exothermic mixing and excess molar enthalpies exhibited a minimum in the CO2-rich region.
This phenomenon is likely arising from the interaction effects occurred by mixing condensate and DSO which results in breaking of chemical bonds and increase the total volume after mixing, leading to excess molar volume greater than zero [28].
The first is described as ideal silicate mixing, the second, showing excess molar volume, is described by ionic associations.
The density, excess molar enthalpy of mixing, HE, and excess molar volume of mixing, vE of piperidine water and pyridine water mixtures were studied at three temperatures, ranging from 294 K to 315 K.
The data were used to calculate the excess molar volumes, showing highly non-ideal mixing behaviour of the binary system of CO2 + H2.
Several predictive empirical relations were applied to predict the excess molar volumes of ternary mixtures from the binary mixing data.
The excess molar entropy was calculated by combining the excess Gibbs function with calorimetric data on the excess enthalpy of mixing from the literature.
Excess molar enthalpies are simultaneously correlated using the Soave Redlich Kwong and Peng Robinson equations of state and the classical mixing rule.
Excess molar enthalpies here reported were correlated using the Soave Redlich Kwong and Peng Robinson equations of state, and the classical mixing rule with two binary interaction parameters.
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