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A low-temperature peak ascribed to reduction of an amorphous copper oxide was detected in TPR patterns of the supported mixed oxides containing Cu. TPR results indicated reduction of Ni- and Co-containing species at temperatures higher than 400 °C; it can be explained by formation of spinel-like phases and high structural ordering of the calcination products.
Mixed oxides containing molybdenum and tin were used for vapour-phase ethanol oxidation.
Masatake Haruta, then working at the Government Industrial Research Institute in Osaka, Japan, tried to make mixed oxides containing gold, and discovered that these materials were remarkably active catalysts for the oxidation of carbon monoxide.
Their thermal decomposition resulted in complex mixed oxides containing periclase-like, CuO and different spinel (Cu1.5Mn1.5O4, CuMn2O4, and MnAl2O4) phases.
Their activities in both reactions were siMixed toxidese of an Al-free unsupported NiMo containingbut their preferenca for the HYD route was higher than that of the latter.
Unsupported A-Mo-W (A = Ni or Co) sulphide catalysts were obtained from mixed oxides containing different W Mo ratios.
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It is suggested that the resulting, electronically conducting oxide is a mixed PbSn oxide containing mainly Pb(IV).
The cascade engineered synthesis of 2-EH was done in a single pot from n-butanal using solventless conditions with trifunctional mixed metal oxide containing 5% Cu and Mg/Al ratio of 3.
Ethanol total oxidation over mixed oxide catalysts containing various transition metal cations was studied.
For convenience of discussion, these are divided into Al2O3 containing mixed oxide supports, TiO2 containing mixed oxide supports, ZrO2 containing mixed oxide supports and other mixed oxide supports containing all the rest.
Alloys exhibiting higher oxidation rates appeared to form mixed oxide scales containing Al2O3 and TiO2, whereby (Al,Cr,Ag 3Ti or α2-Ti3Al phase was formed in the depletion layer beneath the oxide scales.
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