Sentence examples for mixed coordination from inspiring English sources
The mixed coordination species and the higher applied potentials are beneficial for the formation of the well-adhered and dense nickel deposits.
On the basis of the different coordination nature of lanthanide and transition-metal ions, the multifunctional organic ligands with mixed coordination sites such as isonicotinate have been elaborately selected to rationally construct a series of homochrial and achiral 3D Ln M coordination frameworks built from inorganic heterometallic chains with improved thermal stability.
A particular advantage of the chelate, then click synthetic strategy is that the ligand is complexed with the fac-[MI CO 3]+ center prior to cycloaddition with the azide on the peptide, assuring that the fac-[MI CO 3complexed product is obtained as desired without the possibility of mixed coordination species.
Three CO2 adsorption modes were identified on these Co Cu bimetallic clusters: (a) CO2 symmetrically binds the bridge site of the metals through mixed carbon/oxygen coordination with the metal atoms; (b) CO2 asymmetrically adsorbs at the interfacial site via carbon/oxygen metal coordination and hydrogen bonding to the surface hydroxyl; and (c) protonated CO2 at the interface.
A novel luminescent probe based on Ag Cu mixed metal coordination polymer has been designed and synthesized.
The existence of such mixed mode coordination was confirmed by Extended X-ray Absorption Fine Structure (EXAFS) analysis, which was also consistent with adsorption to phosphate sites at low pH, with secondary involvement of carboxyl sites at high adsorption density (high pH).
The edge position of 22 125.9 eV for (nBu4N 2[RuCl3 ox)(NO)] clearly falls in the range of Ru3+ compounds with a mixed nitrogen/oxygen/chloride coordination sphere.
A mixed-metal coordination polymer 7 was obtained by the self-assembly of AgAc, Cu Ac 2 · H2O and pydco.
Additionally, such mixed-ligand coordination assemblies may also be heavily affected by metal ion, synthetic route, and some other external stimuli such as solvent and pH condition, etc.
Two mixed-ligand coordination dimers, [Ni2 pm) (ina)2(H2O)4] (1) and [Mn2(Hpm)2(ina)2(H2O)2]·H2O (2) (pm = tetraanion of pyromellitic acid, Hpm = trianion of pyromellitic acid and ina = isonicotinamide), were comparatively investigated by focusing on their supramolecular architectures.
Three mixed-ligand coordination compounds (CCs) of the formula {[Ag p-abn)(dnca)]·H2O}n (1), {[Ag p-abn)(dnca)]·H2O}n (2), and {[Ag o-abn)4)]·(dnca)·H2O} (3) (where p-abn = 4-aminobenzonitrile, o-abn = 2-aminobenzonitrile, m-abn = 3-aminobenzonitrile, Hdnca = 3,5-dinitrobenzoic acid) were synthesized by reactions of Ag2O and aminobenzonitrile ligands with Hdnca under the ammoniacal condition.
