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Its porosity with nano-sized architectures not only enhance the Fe1-xS redox kinetics, but also can mitigate volume expansion stresses.
Among the efforts to apply SnO2 as an anode, the adoption of carbonaceous materials has been considered as a decent strategy to mitigate volume expansion problem (∼300%) during cycling.
During the electrode fabrication, the submicron Si particles are encapsulated with 3D carbon matrix including a carbon coating on the Si particles and interconnected reduced graphene layers, which can effectively mitigate volume variation of the Si as well as support electrical conductivity.
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The significant improved electrochemical performance of Ge/C-NCF can be attributed to the synergetic effects of the carbon matrix and the N-doped carbon framework: including a highly conductive carbon network and a structure with large porous for mitigates volume changes of Ge nanoparticles.
The composites could effectively improve the kinetics of electronic transportation and mitigate the volume expansion of electrodes during discharge/charge process.
The improved electrochemical performance is mainly attributed to the mesoporous structure and the coating layer of PPy, which effectively mitigate the volume change and enable good conductivity and thus enhance fast charge transfer.
The porous nanotubular structure is expected to mitigate the volume expansion of SnO2, while the as-formed Cu from CuO upon lithiation allows faster electron transport by improving the low conductivity of SnO2.
Firstly, the void space provided by porous structure can mitigate the volume change effect during the repeated charge discharge cycling process, leading to enhanced capacity retention.
This is because the interior hollow structure can provide sufficient space to mitigate the volume change and pulverization, which is caused by the Li+ insertion/extraction [42, 43, 44, 45].
Each of these eight sub-region masks (per slice) was morphologically eroded (using 'imerode' in Matlab) to remove the outermost voxels and mitigate partial volume effects.
To mitigate partial volume effect, white matter mask was created at a threshold of 0.9 after the original probability map was smoothed by a three-dimensional Gaussian kernel with a full-width-half-maximum of 3 mm [ 22].
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