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The composites could effectively improve the kinetics of electronic transportation and mitigate the volume expansion of electrodes during discharge/charge process.
The porous nanotubular structure is expected to mitigate the volume expansion of SnO2, while the as-formed Cu from CuO upon lithiation allows faster electron transport by improving the low conductivity of SnO2.
The improved electrochemical performance is mainly attributed to the mesoporous structure and the coating layer of PPy, which effectively mitigate the volume change and enable good conductivity and thus enhance fast charge transfer.
Firstly, the void space provided by porous structure can mitigate the volume change effect during the repeated charge discharge cycling process, leading to enhanced capacity retention.
This is because the interior hollow structure can provide sufficient space to mitigate the volume change and pulverization, which is caused by the Li+ insertion/extraction [42, 43, 44, 45].
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The porous graphene supported by NF built a conductively integral highway that is preferable for the charge transfer kinetics, while the hierarchical pores from the SnS2 nanoflowers and NF are particularly beneficial for mitigating the volume expansion and promoting electrolyte penetration.
This 3D ordered hollow structure not only offers good electronic transportation routes and ionic conductive channels, but also effectively relieves the stress and mitigates the volume variation during lithiation/delithiation process as reflected by the high cycle stability and excellent rate capability as anode materials for lithium ion batteries.
Based on electrochemical analyses, we determined that Sb acts as an active material, and both Al and carbon create a hybrid buffering matrix that mitigates the volume expansion of the active material during lithiation/delithiation to a greater degree than that by a pure metallic matrix (AlSb).
The excellent performance of the SnS2@CoS2 rGO composite can be ascribed to the rGO acting as a highly conductive matrix and the combined effect of SnS2 and CoS2, which are beneficial for mitigating the volume change and offer fast electron transport due to good electronic contact.
There's no safe way to prevent cows from heeding the call of nature, although some researchers are trying to mitigate the large volume of methane gas cows expel by mixing seaweed into their diets or tinkering with genetics.
The RGO not only serves as a soft and robust matrix to mitigate the large volume change during cycling but also acts as the electron highway.
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