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Electrochemical impedance spectra show that the composite of x = 0.25 has the minimum charge transfer resistance in the initial several cycles.
The charge transfer impedances have the rather similar trends with the ohmic resistance and the MFC with seven bi-layers has the minimum charge transfer resistances for both the anode and cathode electrodes.
The DMFC test results indicate that the MEA prepared from Pd3Co/C cathode exhibits better performance compared to the MEA prepared from Pt/C (Electrochem) and an in-house Pd/C catalyst synthesized, in terms of maximum power density and minimum charge transfer resistance.
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Moreover, it showed the highest photocurrent effect and the minimum charge-transfer resistance.
Single cells fabricated with electroless AAL show lowest polarization (~ 0.3 Ω.cm2) with minimum contribution of charge transfer and concentration polarization.
The results also demonstrated that the effect of phytic acid was not monotonous with increasing concentration: the passive current density ip was minimum and the charge transfer resistance Rt was maximum for the sample obtained from the bath with 0.2 g/L phytic acid, indicating that the sample obtained from the bath with 0.2 g/L phytic acid showed the best corrosion resistance.
In contrast, the average charge transfer over five minimum energy configurations in the gas phase was 0.10, similar to other studies.
The charge transfer resistance between the cathode material and PEG reaches a minimum at 60°C and it does not decrease with a further temperature increase.
Chemisorption barrier and partial charge transfer to the metal for transition between the two potential minima have been examined and compared with experimental data.
The results allow us to determine the minimum Pt film thickness necessary to achieve a relevant reduction of the sheet resistance and charge transfer resistance, which preserve a significant electrode transparency.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com