Monosubstituted arenes adopt a pose in which the alkyl chains maximize the London dispersion interactions with minimal steric clashes, giving an explanation for the observed trend in the benzylic hydroxylation yields.
The remaining panels in Figure 5 depict the wild-type structure and middle X residue rotamers with minimal steric clashes for the most efficiently glycosylated site (cysteine), oppositely charged residues (arginine and glutamic acid), and the worst consensus site (tryptophan).
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Major clashes have been minimal.
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Health workers in Congo must navigate violent clashes, extreme poverty and minimal infrastructure, all of which can hinder drug delivery and patient checkups in rural and isolated areas of the country.
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Clashes of such nature, however minimal, could be perceived as intrusive as we noticed in this study (35).
While the Trp residue does closely approach the portion of the folate substrate containing the methylamino linkage, minimal alterations in the protein geometry are able to relieve the clash.
"We are pleased to announce that no major clashes or arrests occurred, and police presence was minimal".
