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Fractured samples, rinsed to remove mineral plates, reveal separated collagen fibrils on the fractured surfaces.
AFM images of pristine fractured surfaces reveal a dense array of mineral plates.
Contact angle was measured on aged sandstone mineral plates (Fig. 9) for various nanoparticle solution concentrations at room condition.
Figure 11 shows the evolution of wettability changes when sandstone mineral plates are in contact with different concentration of nanoparticle solution.
The mineral plates on the collagen fibrils overlap and exhibit a large range of plate diameters from 30 to 200 nm.
In other regions, the existence of the underlying collagen fibrils can be inferred from the linear patterns of the mineral plates.
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Open image in new window Fig. 9 Mineral plate form sandstone core plug.
Sandstone mineral plate was aged for 3 weeks to be made almost oil-wet, at 90 °C.
The contact angle of oil droplet placed under a mineral plate of sandstone submerged in an aqueous phase is measured, Fig. 10.
The mineral plate thickness, predominant orientation and degree of orientation of the mineral crystals were calculated for each scattering image as described earlier [35 37].
No differences could be seen between the mineral plate thickness in the three groups when calculated using the Bünger method (Wt = 3.24 ± 0.26 nm, Stop = 3.20 ± 0.15 nm and Rescue = 3.31 ± 0.12 nm).
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