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Therefore, mimicking the active site of CA is of enormous interest among the scientific communities.

Receptors for ACT and ETOX were created in the hydrogels by mimicking the active site of the metallo-enzyme, using 1- or 4-vinylimidazole (1VI or 4VI) and N-hydroxyethyl acrylamide (HEAA) as functional monomers.

The results revealed that the enzyme-free detection method using CuZn nanoparticles can determine superoxide radicals with high performance compared to other detection methods prepared with different nanoparticles by mimicking the active region of superoxide dismutase enzyme.

The DFT/B3LYP/6-311+G (d,p /LANL2DZ method has been used to calculate the geometry and electronic structures and 51V and 17O NMR chemical shifts of a series of 7 oxo-peroxo vanadium (V) complexes mimicking the active site of vanadium bromoperoxidase (VBPO) in the gas and solvent (acetonitrile) phases.

This is the case for coronatine produced by several plant pathogenic Pseudomonas species mimicking the active natural -7- iso-jasmonoyl l-isoleucine [ 38].

To test the interaction of this dimer with Def1, pure recombinant Def11 500, mimicking the active pr-Def1 fragment, was immobilized on beads.

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Similar(52)

These biomimetic complexes (Co Im@MS and Zn Im@MS) mimicked the active site of carbonic anhydrase and showed an enhanced catalytic activity in CO2 hydration.

The possibility of the obtained redox-active macromolecules to mimic the active site of certain copper-containing enzymes capable of reversible binding and activation of dioxygen is discussed, providing some insight into the mechanism of the catalytic process.

IFABP-PX mutants were further optimized by introducing lysine residues in order to mimic the active site of native transaminases.

To date, considerable progress has been made to synthesize highly active and stable heterogeneous electrocatalysts whose structures mimic the active sites of such natural catalysts [32 34].

In this study, peptides containing a cysteine thiol and histidine imidazole group were designed to mimic the active site of the cysteine protease papain.

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