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Increasing the milling time to 20 and 30 h also reduced the temperature of hydrogen desorption.
In addition, further increasing the milling time to 60 min did not remarkably decrease particle size (Additional file 1).
With an increase in milling time to 240 h, the nickel clusters or particles disappeared and a new monophase alloy with amorphous structure was formed.
By increasing the milling time to 20 h for the catalyst containing MgH2, the free surface area and mean pore volume decreased and the mean diameter of the pores increased.
Extending the milling time to a minimum of 10 h led to a suitable sharper bi- and tri-modal distributions below the nozzle limit with d 0.5) = 0.129 µm for GDC ink and d 0.5) = 0.443 µm for NiO ink.
The conditions of adjusting the temperature of soaking to 50 °C, soaking time to 36 min and milling time to 8 min and 10 s would favor maximum response value obtainment.
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The bottom ash was pulverized using a high energy vibratory ball mill at two different milling times to achieve a particle fineness approximately two and three-times finer, respectively, than type I cement.
Figure 3 shows plots of the coherent domain size (see also Table 2), extracted from the X-ray diffraction data at different ball milling times, to the first, second and third powers against the monomeric sugar yields obtained following 72 h of enzymatic saccharification.
Figure 8 shows plots of the coherent domain size (see also Table 2), extracted from the X-ray diffraction data at different attritor milling times, to the first, second and third powers, versus the monomeric sugar yields obtained following 72 h of enzymatic saccharification.
The increase in the milling time up to 30 h led to the fracture of large particles, resulting in an increase in free surface relative to the 20 h-milled sample.
The XRD patterns of as-received MgH2 and ball-milled MgH2 show that increasing the milling time led to an increase in the width and reduction in the intensity of peaks.
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