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The adsorption of the inhibitor onto the mild steel surface is enhanced at higher TNC values.
These values are negative signifying that the adsorption of guar gum on mild steel surface is exothermic.
The adsorption of 2-chloro 3-formyl quinoline on mild steel surface is exothermic and obeys the Freundlich adsorption isotherm.
As a result, the adsorption of guar gum on mild steel surface is steady with the mechanism of physical adsorption.
On the other hand, it is well known that the mild steel surface is positively charged in the acidic media [64].
The formation of an adsorbed protective film of the inhibitor molecules on the mild steel surface is confirmed by scanning electron micrographs (SEM), which proves that the guar gum acts as good inhibitor at 1N acids concentration.
The thermodynamic parameters such as heat of adsorption (Qads) and free energy of adsorption (ΔGads) suggested that the adsorption of inhibitor on the mild steel surface is exothermic and followed by spontaneous process.
Obtained results show that the inhibition efficiency increases with the increase in concentration but decreases with the temperature rise, and adsorption of FP gum on mild steel surface is exothermic and spontaneous which favours the physical adsorption and is found to obey the Langmuir adsorption isotherm [58].
Corrosion inhibition mechanism of two mercapto-quinoline Schiff bases, eg., 3- phenylimino methyl)quinoline-2-thiol (PMQ) and 3- phenylimino methylylimino)methyl) quinoline-2-thiol (MMQT) on mild steel surface is investigated by quantum chemical calculation and molecular dynamics simulation.
∆Gads of the inhibitor on mild steel surface was determined by the following formula: Fig. 6 Adsorption isotherms for the guar gum on mild steel in different acid medium at 304 K temperature.
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