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Migration of organic chemicals through composite liners is calculated using a 1D diffusion model.
Our previous studies revealed that the topography and intrinsic properties of different fractions of organic matter in a mountain lake environment affect the distribution and migration of organic substances (Chen and Chiu 2000).
Over the past two decades, a number of models have been developed to describe the multiphase migration of organic chemicals in the subsurface.
Molecular hydrogels have attracted extensive research interest because of their great potential for tissue engineering, migration of organic and inorganic material, drug delivery as well as a miniaturized method for application on biological samples.
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The source of organic matter is unknown, but probably it is derived from the surrounding sedimentary terrain, where the hot hydrothermal fluids generated the migration of organics.
Silica gel and polyaniline modified silica gel were used as stationary phase while the different formulations based on aqueous solutions of ionic liquids such as 1-methyl-imidazolium chloride, 1,2,3-trimethylimidazolium methyl sulphate and 1-ethyl 3-methyl-imidazolium tetrafluoroborate were used as mobile phase to study the migration behaviour of organic dyes.
A simplified solution to predict the migration of volatile organic chemical due to the gas density effect has shown that a high source concentration may lead to significant downward advective gas-phase transport in a soil with a high air-permeability.
This strongly supports a two-stage adsorption mechanism for organic solutes, involving initial migration of small polar organic molecules to the mineral surface followed by water film displacement due to co-adsorption of the more apolar organic compounds, thus converting an initial water-wet mineral system to an organic-covered surface.
The tendency of the high concentration organic plumes to migrate downward under gravity forces is also demonstrated, and is shown to enhance migration of aqueous phase organic into regions of low permeability, causing substantially increased concentration tailing.
Migration of inorganic and organic chemicals in compacted clay liners is calculated using a solution of the 1D advection dispersion-reaction equadvection dispersion-reaction
The results demonstrate that the use of estimated transport relationships produces significantly different predictions of organic liquid migration.
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