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These types of treatments are necessary to avoid the progressive migration of compounds from the bulk to the surface, which can occur over time [25].
Freeze-drying considerably reduces the volume of the liquid phase while it increases the volume of the gas phase, which seems to promote the migration of compounds to the headspace of the vial.
We know that the migration of compounds from the urine, or liquid phase, to the headspace of the vial, or gas phase, depends on the volume of the liquid phase, the volume of the gas phase and the affinity of compounds for the liquid and gas phases [18].
Furthermore, considering the TLC separation pattern, the more purification steps that were performed the better the observed separation and migration of compounds was (data not shown).
Similar(56)
Despite greater current speeds on the channel bank, smaller tidal asymmetry leads to slower migration of compound dunes.
Concurrent migration of compound dunes and the tributary channel produced a complicated stratigraphic architecture consisting of a point-bar succession overlain by a coarsening-up compound-dune succession.
Band broadening in chromatography results from the combination of the dispersive effects that are associated with the different steps involved in the migration of compound bands along the column.
This can be justified due to partition coefficient (K) of these compounds resulting in the migration of phenolic compounds during partitioning process of liquid-liquid extraction [ 49].
Migration of 43 compounds including terpenes, alkanes, plastic additives and degradation compounds is reported.
Hence, migration of gasoline compounds in the liquid phase (non-aqueous or dissolved phase) did not occur during this experiment.
This method is based upon the electro-kinetic migration of ionized compounds by the application of an electrical potential difference.
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