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The results revealed that for mechanically induced grain-boundary motion there is a misorientation dependence of migration activation parameters.
The boundary motion was measured in the regime between 330 °C and 415 °C, and the corresponding migration activation parameters were determined.
The migration activation parameters for the investigated curved ⟨10¯10⟩ tilt boundaries moving under a capillary driving force were distinctly different from the corresponding parameters obtained for magnetically driven ⟨10¯10⟩ tilt boundaries with similar misorientation angle.
The migration activation parameters of all investigated boundaries comply with the compensation law, i.e. there is a linear relationship between the activation enthalpy and the logarithm of the pre-exponential mobility factor.
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The temperature dependence of the boundary migration rate was measured and the migration activation energy determined.
The migration activation enthalpy was found to vary between 1.18 and 2.15 eV.
Whitesides, G. M., Houk, J. & Patterson, M. A. K. Activation parameters for thiolate disulfide interchange reactions in aqueous-solution.
Furthermore, a stronger lattice-size dependence is found in the deposition/migration model when the migration activation energy contribution from each neighboring particle becomes significant.
Activation parameters explain the corrosion process.
The activation parameters reveal that the activation energy increases as the concentration of Tilia cordata increases.
This interpretation is supported by the activation parameters.
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