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Novel fabrication techniques have enabled increasingly controlled microstructural geometries in electrochemical energy devices, including dye-sensitized solar cells.
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In this contribution, we present digital image analysis and microstructure modeling tools that can provide useful input for microstructure sensitive design of materials through incorporation of the detailed microstructural geometry in the simulations of materials behavior.
An adapted version of this tool is presented for analyzing the performance of microstructural geometry in dye-sensitized solar cells.
The micromechanical model provides three-dimensional (3D) effective properties of homogeneous composite responses, while recognizing microstructural geometries and in situ material properties of the heterogeneous medium.
This electrochemical fin model is capable of describing experimentally observed performance gains associated with specific microstructural geometries.
The model presented is capable of replicating experimentally observed electrode behavior inclusive of sensitivity to microstructural geometry, which stands in contrast to existing models that apply governing equations analogous to a constant cross-section thermal fin equation.
The basic uncertain microstructural properties considered in the investigation are the microstructural geometry and orientation, the local relative density and the local pore size distribution.
For an existing heterogeneous material, microstructural geometry was taken into consideration using a simple geometrical parameter for the inhomogenity and the representative volume element (RVE) in which the inhomogenity was embedded.
Attributes of three-dimensional microstructural geometry have dominant influence on the mechanical behavior of materials.
The microstructural geometry is reconstructed from focused-ion-beam scanning-electron-microscopy (focused-ion-beam scanning-electron-microscopy
The microcapsules size and shell wall thickness reflect the microstructural geometry at definite volume fractions.
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