Sentence examples for microscopic reverse of from inspiring English sources

However, I am only familiar with this argument when the forward and reverse rates are the rates for reactions that are the microscopic reverse of each other.

This large separation suggests that, after acetate departs, the thiocarboxylate group of CysO occupies the acetate binding site and that thiocarboxylate addition is the microscopic reverse of acetate departure.

Indeed, it is even quite unlikely that a direct reaction of H2 with E0 to form E2 (eq 2) would be the microscopic reverse of the E2 → E0 relaxation with accompanying loss of H2.

The rate of synthesis of ATP from ADP (the microscopic reverse of hydrolysis) is neglected here because it was experimentally proven to be below the level of detectability even in the presence of the hydrolysis-accelerating JDP cochaperones (Russell et al., 1998), that is k synth ≤10−6 s−1.

The following question is commonly raised: If electrons accumulated in E n intermediates, n = 2 4, can relax to E n -2 through formation and release of H 2 during turnover, as captured in the partial LT scheme, Scheme 1, why does the enzyme not exhibit the reverse of this reaction, and react with H2/D2 in what might appear to be the "microscopic reverse" of H2 release?

The reduction of E0 by H2 (eq 2) by the microscopic reverse of this two-step relaxation would correspondingly take place in two steps, Figure 7, with the initial E0 → E0′ thermal activation associated with the conformational change, MN → MN′, adding an activation free energy (denoted |Δ G†|) and kinetic barrier to the endergonic reduction of E0′ → E2 by H2 (free energy denoted |Δ Gh′|).

Based on the principle of microscopic reversibility, metal rescue of the leaving group in this reverse reaction indicates that a metal activates the nucleophile in the second step of the forward splicing reaction.

Oversold: The reverse of overbought.

Installation is reverse of removal.

The microscopic rate constant of the reverse inactivation of the enzyme (k-0) in these experimental conditions are listed in Table 1.

All isolates were previously identified as S. schenckii by means of morphology (macro and microscopic studies), ability of isolates to reverse to yeast-like cells at 37°C, and serological tests to patients from where they were isolated, all performed in the Mycology Laboratory at Instituto de Biomedicina, Caracas, Venezuela, a national reference center for skin diseases.