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The optimized palm shell activated carbon with surface area of 973 m2/g, total pore volume of 0.78 cc/g and micropore fraction of 70.5% showed an excellent agreement with the amount predicted by the statistical analysis.
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The macropore and micropore fractions of the gels were estimated from the masses of total water and water accessible to the largest solute.
The good rate performance is provided by the relatively low micropore fraction (20 30 % independently of the surface area of the carbons, see Table 1) giving almost complete availability of the carbon surface for the electrolyte ions.
Quadratic models were developed for surface area, total pore volume, and microporosity in term of micropore fraction.
In this study, we took advantage from the evolution of the micropore fraction in the mesoporous silica with the autoclaving temperature of synthesis.
Variation of the preparation conditions allowed to obtain carbon materials with surface area varied in wide range, from 540 to 3060 m2/g and, which should be emphasized especially, with close values of the micropore fraction (20 30 %).
The micropore fraction varied from 0.38 to 0.47.
The activated carbons produced were characterized by carbon yield, BET surface area, porosity development (total pore volume and micropore fraction).
In accordance with a micropore filling mechanism, the fraction of these distributions available for TCE sorption decreased with decreasing P/Ps.
It enlarged the overall surface area by introducing a significant fraction of micropores and small mesopores.
The high surface area and the existence of a large volume fraction of micropores both contribute in concentrating the analyte vapors in the sensor.
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