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The linear ABA type copolymers showed micro phase separation and thermoplastic elastomer (TPE) behavior only at very high PS content.
Porous membranes are prepared through micro phase separation of immiscible polymers consisting of hydrophobic polymer (polystyrene) and hydrophilic polymer (poly 2-vinylpyridine)).
The two ingredients were found to form independent networks despite changes in the SPI microstructure, which were attributed to micro phase separation.
ESR results indicated that the probe molecule: Tempo couldn't give clear micro phase separation or miscibility information and thus was not sensitive to the investigated polymer blends system.
In contrast the specific brush type molecular architecture seems to prevent the micro phase separation of the PBA and PS components, resulting in amorphous bulk material with single glass transition temperature.
PET/PEI films are melt miscible consequently the addition of PEI to PET increases the glass transition temperature while slightly broadening it as a result of partial micro phase separation.
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AFM and DMTA support micro-phase separation in the three systems and provide complementary information on the crystalline habits in the phase-separated domains of the blends.
The sulfonation brings about a disturbance in micro-phase separation in SSEBS.
This result suggests the existence of a micro-phase separation in the crosslinked collagen matrix.
Micro-phase separation was not observed when films were annealed at 120 °C, at which temperature the high crystallization rate of PLLA overwhelmed the micro-phase separation process.
At this time, micro-phase separation and turbidity will occur, so the light transmittance is almost zero.
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