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This bacterium formed methyl acetate from the latter with a BVMO, which was subsequently hydrolyzed to methanol and acetate.
In the context of the production of n-butyl acetate, acetic acid or ethyl acetate from methyl acetate, a pervaporation module was employed in order to retrofit the extractive distillation unit used to recover methyl acetate from a methanol/methyl acetate industrial waste stream.
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An ignition delay time correlation for methyl acetate (MA) from a previous study is also employed in the comparison.
The separation performance efficiencies of polydimethylsiloxane (PDMS -based (PDMS -based0, PERVAP™-075, and PDMS 040603) and PDMSoctylmethylsiloxane (POMS)-based (POMS 04-075) organoPDMSic composite membranes were investigated, examining the amount of methyl acetate recovered from binary methyl acetate–methanol mixtures.
Methyl acetate (MeOAc) recovery from the polyvinyl alcohol (PVA) production is a difficult and heavy energy consuming process.
The standard enthalpy of formation and standard entropy of liquid cyclopentene, acetic acid, methanol, methyl acetate and cyclopentanol were adopted from the data handbooks [7, 8], the results are shown in the Table 4.
The liquid heat capacities of cyclopentene, acetic acid, methanol and methyl acetate at the temperature range from 273.15 to 373.15 K were taken from the data handbook [9, 10], and the expression of liquid heat capacities was fitted as multinomial; the results are shown in Table 2.
However, several significant differences manifest themselves upon switching from the well documented aqueous methanol carbonylation to the anhydrous methyl acetate carbonylation to acetic anhydride.
Then aldehyde 132 reacted with the enolate derived from methyl acetate in THF to give 133.
The plasticizers studied included a wide range of chemicals from methyl acetate to di-undecyl phthalate.
This work explores an alternative to convert methyl acetate back to acetic acid (raw materials of PVA plant), methyl acetate (MeAc) hydrolysis.
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