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The relative standard deviation (RSD) of the method under optimum conditions was 3% (n = 5).
The relative standard deviation (RSD) of the method under optimum conditions was 5.0% (n = 8) for all metal ions.
Analytical merits of the method, under optimum conditions (extraction temperature: 50±1 °C, extraction time: 15 min, desorption temperature: 250 °C, desorption time: 2 min, solution pH: 1.5, salt concentration: 5 mol L−1), are 70 μg L−1 and 0.20 100 mg L−1 for LOD and LDR, respectively.
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Capillary free zone electrophoresis is perhaps the only separation method, which, under optimum conditions, gives a plate number not far from the theoretical limit.
The linearity, LOD and LOQ of investigated analytes were determined by MEKC method under the optimum conditions.
The developed method was examined under optimum experimental conditions and the obtained results revealed a linear relationship between the relative CL intensity and the investigated drug at a concentration range of 1.0×10−9-1.0×10−2 moL−1−1, (r = 0.9993, n=9) with detection and quantification limits of 1.6×10−11 and 1.0×10−9 mol L−1, respectively.
So, the combination of these two methods under their optimum condition was used to prepare nanofluid with the same loading of functionalized nanoparticles.
The optimization result shows the feasibility of this method, and the simulation under optimum parameters reveals that the LPM can get the same precision as transfer matrix method (TMM).
Under optimum conditions, method showed good linearity in the selected range (R 2 from 0.993 to 0.995).
It is worth mentioning that due to the dense film quality nature of the IBSD method, the TiAlN films deposited under optimum conditions (PN2 = 4.4 × 10−3 Pa) exhibited good thermal stability up to 700 °C in an oxygen atmosphere and the resistivity remained lower than 500μΩ × cm.
Under optimum condition, the method has wide linear calibration rang (0.5 1700 ng mL−1) with reasonable detection limit (0.13 ng mL−1) and R2 = 0.9971.
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