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Methanol yield of about 7%–8% was obtained in gas phase partial oxidation.
The methanol yield of 11.4% was achieved at 350 °C for 3 h with Cu 70 mmol, Zn 60 mmol, HCl 2.0 M and water filling 50%.
A maximum methanol yield of 454.6 μmole/g-cat·h is achieved under a liquid flow rate of 50 μL/min, 0.2 M NaOH, and the light intensity of 8 mW/cm2.
The experiment results showed that 23.2% AgBr/TiO2 had relatively high reduction yields under visible-light irradiation for 5 h, with a methane yield of 128.56, methanol yield of 77.87, ethanol yield of 13.28, and CO yield of 32.14 μmol g−1, respectively.
At higher temperatures (200 °C) however, Cu-FER and Cu-BEA showed comparable methanol yields as Cu-ZSM-5 and also the methanol yield of Cu-MOR increased at this higher reaction temperature, indicating that a second not yet identified Cu-oxygen species is activated in the FER, BEA and MOR zeolites at higher temperatures.
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Higher than 1.2 wt.% Cu loading gave a lower rate of methanol yield because of the masking effect of Cu2O clusters on the TiO2 surface.
At the applied potential of −0.59 V, pyridine concentration of 10 mM, and pH of 5.2, higher methanol yield can be obtained at CuInS2/graphene hybrid thin film electrode; and the rate of methanol formation at CuInS2/graphene hybrid thin film electrode is about 1.4 times that at CuInS2 thin film electrode.
Trituration of the foam with methanol yielded 2.71 g of white crystals.
The column chromatography of methanolic extract residue in chloroform with increasing polarity of methanol yielded two major marker compounds picroside I [6-0-trans-cinnamoyl catalpol] and picroside II [6-O-vanilloyl catalpol].
This showed that the natural extract and the polyphenolic compounds are water soluble but the addition of methanol yielded the most active fractions.
The presence of 0.1% methanol yielded a poor expression rate at the detection limit and was observable only after 3 days of induction.
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