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The crossing of methanol through the membrane leads to the reduction in the OCV value.
In all models the dominating physico-chemical phenomenon is the transport of methanol through the membrane, causing cathodic overpotential overshooting.
The model also accounts for the undesired cross-over of methanol, through the PEM, towards the cathode catalyst layer.
The proton conductivity and the permeability of methanol through the block-type PEMs decreased with increasing GA concentration.
Open image in new window Fig. 2 Error versus number of hidden layer for a water and b methanol through the best obtained MLP network.
The selective removal of methanol through the catalytic membrane inhibited the unfavorable reverse reaction (MTBE synthesis), and at the same time accelerated the MTBE decomposition reaction.
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The differences in the concentration of methanol result in methanol crossover through the membrane, and methanol permeability can be determined.
It is shown that the key issue regarding the methanol supply is how to feed high-concentration methanol solution but with minimum methanol crossover through the membrane so that both the system specific energy and cell performance can be maximized.
The FGO can effectively hinder the methanol passing through and enhance the water retention by its special sheeted structure.
The temperature dependence and methanol concentration dependence studies both suggest increased methanol permeation through the thinner supported catalyst layers relative to the unsupported catalyst layers.
It is shown that the critical challenge regarding to minimize methanol crossover through the membrane using various hybrid membranes and methanol transport barrier so that the cell performance can be maximized.
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