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Using isotope-labeling experiments involving 12C-alkene and 13C-methanol, a clear tendency for methylation of the co-reactant alkene with methanol is observed with progressive deactivation of the catalyst.
In contrast, on clean Cu hardly any conversion of methanol is observed.
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The highest selectivity and space time yield to formaldehyde and methanol were observed at lower FePO4 loading levels for the SiO2, ZrO2, and TiO2 supports.
No amount of methanol was observed in the food products.
Although the synthetic procedure and the recrystallization process of complex 1 were performed in methanol, a marked preference for coordination of water over methanol was observed and proved by single crystal X-ray determination.
The results showed some level of methanol in some of the studied local and foreign alcoholic drinks between the ranges of 0.003-0.161% Vol. whereas no methanol was observed in any of the analyzed food products.
To our surprise, no growth with methanol was observed in the syntrophic co-culture.
Higher yield with methanol was observed with bark, fruit (with seed) and seed.
Interestingly, we also found that the alkylation of valerophenone by methanol was observed at temperatures as low as 65 °C,[ 18] implying that methanol dehydrogenation was taking place under these relatively mild conditions.
Therefore, only a small catalytic effect of UPD-lead on methanol oxidation is observed.
Complete charge transfer is observed in methanol for |Δχ| < 0·3, and electrostatic adsorption without charge transfer takes place for large |Δχ|-values.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com