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Under the optimum conditions, methanol conversion of 34.5% and carbonylation selectivity of 94.7 mol% are obtained.
Under these conditions, the overall efficiency of AMR is maximal and equals 57%, and the hydrogen production rate achieves 30.6 L/h at the methanol conversion of 82%.
The system was also ran for more than 100 h at 453 K, at 0.3 A cm−2, with a methanol conversion of >90%.
The sample prepared under optimized conditions showed a favorable surface area of 251.5 m2 g−1, pure γ-alumina crystallite phase and a methanol conversion of 78.2%.
Yaripour et al.18 studied the effect of modification of γ-Al2O3 with (0 15%) SiO2 and reported the % methanol conversion of 64.9% for the unmodified γ-Al2O3 at a reaction temperature of 300 °C and LHSV = 15.6 mL/(h gcat).
Among these three configurations, the flow through catalytic membrane reactor demonstrates the maximum methanol conversion of 36.4% and 100% selectivity toward DME.
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Methanol conversions of higher than 99% were obtained even at comparatively low transpiring water temperatures (125 250 ° C).
The 0.70 wt% Pt2.42Co/meso-MnOy sample performed the best: the T50% and T90% (temperatures required for achieving methanol conversions of 50 and 90%%, respectively) were 50 and 86 °C at a space velocity of 80,000 mL/(g h).
The analysis of methanol conversion to CO2 was performed with aid of differential electrochemical mass spectrometry (DEMS).
The selectivity of methanol conversion to hydrocarbon has been found to be a function of CuO/ZnO/HZSM-5 concentration.
The corresponding molar fraction of hydrogen can reach about 62.6%, which corresponds to methanol conversion rate of 72.6%.
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