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As it is, methanol can be deadly.
Methanol can be produced from different sources.
Methanol can be used as a gasoline additive or gasoline substitute.
Methanol conversion was nearly complete and the self-decomposition of methanol can be suppressed significantly.
Consequently, methanol can be oxidized more efficiently and the performance of DMFC increases.
The derived methanol can be further converted to gasoline via a methanol to gasoline (MTG) process.
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The differences in the concentration of methanol result in methanol crossover through the membrane, and methanol permeability can be determined.
Laffineur et al. (2012) developed a theoretical framework to simulate methanol exchange at Vielsalm and showed that the bi-directional nature of methanol exchange can be explained by adsorption/desorption of methanol in water films within the ecosystem (aided by the low Henry constant of methanol) and a postulated sink process.
Due to the low methanol crossover of the LE-DMFC, a highly concentrated methanol solution can be directly fed into the LE-DMFC.
At the applied potential of −0.59 V, pyridine concentration of 10 mM, and pH of 5.2, higher methanol yield can be obtained at CuInS2/graphene hybrid thin film electrode; and the rate of methanol formation at CuInS2/graphene hybrid thin film electrode is about 1.4 times that at CuInS2 thin film electrode.
As methanol crossover can be reduced, but cannot be completely eliminated, efforts should be focused on reducing the adverse impacts of permeated methanol on the cathode, i.e.: the problems of mixed potential and Pt poisoning.
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