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In this study, 90 and 250 kDa CMC polymers were modified with functional methacrylate groups and photocrosslinked to produce hydrogels at different macromer concentrations.
The bilayer permeability of the polymersome is decreased by increasing the packing density of the bilayer with methacrylate groups and is further decreased by inducing chemical cross-linking reactions between the methacrylate groups.
Following this, 2,2′-azobis isobutyronitrile) (AIBN, Sigma) was added, and the mixture was placed on a hot plate at 70 °C for 2,2′-azobis isobutyronitrilepolymerizAIBNn of the methacrylate groupSigma evaporate the THF solvent.
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The surface of imogolite was modified with 2-acidphosphoxyethyl methacrylate, which has a polymerizable methacrylate group and a phosphoric acid moiety, before preparation of polymer hybrid.
At this level nearly all molecules are likely to have at least one methacrylate group and over 80% have two.
Therefore, in the present study, a thermoplastic polymer blend of poly(hydroxymethylglycolide-co-ε-caprolactone)/poly(ε-caprolactone) (pHMGCL/PCL) was functionalized with methacrylate groups (pMHMGCL/PCL) and covalently grafted to gelatin methacrylamide (gelMA) hydrogel through photopolymerization.
A new dimeric triarylmethine-based dye, Ac-BTM-DHFMS, substituted with methacrylate groups, was designed and synthesized to improve thermal and chemical stability by using polymerisation of the acrylate cross-linking group.
Then, MIca was dispersed uniformly in HAMA solution and covalently introduced into HAMA by the reaction of methacrylate groups between HAMA and MIca during the formation process of hydrogel.
Separately, PHEA-C18-MA without methacrylate groups (PHEA-C18) and unalkylated poly 2-hydroxyethyl aspoly 2-hydroxyethylere synthesized aspartamidePHEAmers.
Silane coupling agents allow improved resin wettability of the etched ceramic surface and provide a covalent bond with the methacrylate groups in the resin and the ceramic surface [4, 5].
When the equilibrium water content of the dextran phase was 70%, the final conversion of methacrylate groups was around 90% and was reached within one hour, even at relatively low concentrations of KPS and TEMED.
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