The iron tetrasulfophthalocyanine showed an activity from far superior to that of the other metallic complexes and to the corresponding homogeneous catalysts.
The inhibition efficiency of the benzimidazole (BPP_1 7) derivatives depends on many factors, including the molecular size, heat of hydrogenation, mode of interaction with copper electrode surface, formation of metallic complexes and the charge density on the adsorption sites.
This review summarizes the first experimental and modelling studies that display and tentatively describe the effects of different radio-enhancers, including metallic complexes and NPs, used to improve the performance of particle beam treatments, e.g. protons, helium and carbon ion radiation.
While dissolving minor levels of organic matter and metals, the maximum dispersion treatment liberated large amounts of small particles (< 2 μm) that were enriched in N-rich organic matter, SRO mineral, and organo-metallic complex and that accounted for 48% of total mass, 63% of C, N, and 72 to 91% of extractable phases of Al, Si, and Fe by pyrophosphate and acid-oxalate.
Therefore, the same metallic complex could be used as photoinitiator of vinyl polymerization and as molecular probe to sense the hydrogel microenvironments.
The microenvironments present near linear polymers and inside crosslinked gels were investigated by measuring fluorescence lifetimes and steady state anisotropy of the metallic complex (Ru bpy)3+2, present in the solution.
The design of the materials relies on an addition monomer having a terpyridine moiety, which behaves as a dye in presence of transition metal cations due to its proven chelating capability towards these species and the colour development that always accompany the metallic complex formation.
The effect of sorbed water vapor on the electrical response of a ceramic, metallic complex oxide (KSbMoO6) with characteristics of ionic conductor has been studied by means of several experimental techniques aiming to explore its application as a humidity sensor.
The method is based on sequential preconcentration of Cr VI) at pH 5.0 onto mesoporous amino-functionalized Fe3O4/SiO2 nanoparticles followed by cloud point extraction of Cr III) as metallic complex with 4- 2-thiazolylazo)resorcinol (TAR).
It is possible that this metallic complex adds stability to the structure.
The antitumor effect of C7a was also tested against human tumor cells, comparatively with cisplatin, the standard metallic complex used in chemotherapy.
