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The electronic band structure in Fig. 3d indicates the metallic character of Li2NbS4.
This clear metallic character of the DOS for nanocones is more robust for the two-pentagon CNC [22, 26].
However, the IR modulation efficiency is markedly affected as a consequence of the increased metallic character of the semiconducting phase.
The 13C-NMR of CO on Pt and Pd reveals the metallic character of the bond.
The EIS spectrum (inset Fig. 4d) exhibits that Ni2P has a very low RCT (~ 7.3 Ω), indicating the metallic character of Ni2P.
Comparison with surface properties of supported MoS2 points to the lower acidic and higher metallic character of Mo sites of the unsupported sulphide.
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For technological purposes it is desirable to design interfaces where the peculiar half-metallic character of NiMnSb is not degraded.
Using first-principle calculations method based on spin-polarized density functional theory, we have predicted the half-metallic character of the AMnSe2 (A=Rb, Cs) layered compounds.
On the other hand, the half-metallic character of Ni-doped blue phosphorene predicted by PBE is preserved in the PBE + U band structure (see Fig. 6), because the bands crossing the Fermi level have relatively larger band widths compared to those in Ti-doped blue phosphorene (see Fig. 5 b).
These materials, with an intermediate band of a metallic character, are of great interest as new high-efficiency materials in solar cells.
Writing early in the history of intermetallic compounds, the British metallurgist Cecil Desch observed that "certain non-metallic elements are capable of forming compounds of distinctly metallic character with metals, and these elements may therefore enter into the composition of alloys".
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