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The Cu metal surface area increased with increasing copper concentration in the deposition bath solution.
The Cu metal surface area was measured by the selective chemisorption of nitrous oxide.
Characterization data of "steady-state" catalysts show significant surface coverage by CO2 irrespective of metal surface area (MSA).
The influence of the reduction atmosphere (5 or 100% H2) on metal surface area (MSA) and activity pattern has been probed.
Pre-purification of the electrolyte had no significant influence on the metal surface area available for H adsorption determined immediately after an electrochemical cleaning step.
The optimized sample of NiNC-4 contains Ni nanoparticles of 2.02 nm in size which afford a large metal surface area of 400.7 m2 g−1 and a high nitrogen content of 7.21 at%.
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After reduction the three catalysts had similar metal surface areas.
Arrays with metal surface areas of about 1 mm2 or 109 nanoparticles are fabricated by EBL.
DME synthesis experiments showed that the CO conversion and DME yield were linearly correlated with Cu metal surface areas of Cu-Zn-Cr catalysts admixed with γ-Al2O3.
The extent of the oxide/metal interface, probed by Cuδ+/Cu0 and oxide-to-metal surface area (OSA/MSA) ratios, is the key-parameter allowing the normalization of the catalytic specific activity in a wide range (3 60%) of metal dispersion and the consequent structure insensitive character of the CO2 hydrogenation reaction.
The metal surface-area of PtRu catalysts prepared in an identical manner increased significantly with the increase in Ru content.
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