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Hornblendes exhibit typical amphibole structures; these are based on double tetrahedral chains between which four metal sites are located.
The dolomite structure can be considered as a calcite-type structure in which magnesium and calcium cations occupy the metal sites in alternate layers.
Tetrahedral substitution of aluminum for silicon is common and provides charge balance for trivalent and univalent substitution in the metal sites.
Consequently, the glycolaldehyde was hydrogenated into EG on metal sites.
This clearly envisages the significance of both acidic and metal sites for this reaction.
The hydrogenation reactions of tetralin can take place on noble metal sites (Du et al. 2005).
The metal sites led the dehydrogenation of saturated hydrocarbons and increase in olefins.
The glycol molecule deprotonates to form surface alkoxy groups bound to the metal sites.
Propylene was seen to interact strongly with unsaturated metal sites, due to specific π‐Cu bonds.
During the past decade, there are only a few strategies to atomically disperse metal sites on catalyst supports.
Hence, the only rate-determining step is the methane dissociation on the metal sites (C H bond activation).
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