Sentence examples for metal coordination sphere from inspiring English sources

Cycloocta-1,5-diene (cod), a fairly common ligand in organometallic chemistry, is introduced into the metal coordination sphere by ligand displacement reactions; for example,PdCl2 NCPh 2 + cod → codPdCl2 + 2NCPh.

The metal coordination sphere is shown as dashed line.

Elimination of chloride from the metal coordination sphere leads to a self-assembled tetranuclear macrocycle [Rh(COD L1]4[ClO4]4 (2).

The metal coordination sphere comprises of two chelating oxygens from the croconate dianion, two water molecules and two bpds nitrogens located in cis positions.

This spatial structure of the metal coordination sphere makes the Re metal ion kinetically inert towards ligand substitutions which mitigate the metal-DNA interactions [20, 26], hence heavy metal toxicity.

Strong peaks in the 2035 to 1880 cm−1 range in FTIR spectra obtained for metal complexes are characteristic to the three carbonyl peaks in the metal coordination sphere and confirm the presence of the fac-Re(CO) 3 + core [1].

An inner QC layer, treated with DFT, included the active-site metals, key Asp side chains, parts of the primer dC nucleotide, and incoming dUTP nucleotide, along with two water molecules to complete the metal coordination spheres.

The hydrogen bond to the ligand Asp– is within the metal ion coordination sphere and therefore does not bring outside influences to bear upon the OH /H2O.

The metal ion coordination spheres, metal ligand distances, and metal hydration in the alkali metal complexes differ from the magnesium product complex (Supporting Table 2 and Supporting Figures 3 and 5, Supporting Information).

The GO functional groups serve as ligands replacing water molecules from the metal cations' first coordination sphere.

Proper formulation of that metal ion's coordination sphere sets the stage for construction of appropriately configured Schiff ligands based on tromethamine and variably modified vanillin core components.