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All titrations afforded a positive change in entropy, which correlates to an increase in disorder caused by the loss of a water shell around the metal and phosphate compound as the metal coordinates to the phosphate compound.
One Mg2+ (nucleotide binding metal) coordinates two aspartate residues (Asp190 and Asp192) and the triphosphate moiety of the incoming nucleotide, thereby facilitating nucleotide binding.
The catalytic metal coordinates a nonbridging oxygen of the α-phosphate of the incoming nucleotide as well as O3′ of the primer terminus.
We decided to study the oxidative addition of Ar X bonds to [AuXL] by examining systems of type I in which the metal coordinates the phosphorous ligand of a phosphine or phosphite bearing an ortho-halogenated aryl group (Scheme 1).
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Based on available experimental template structures with substrate, phosphate, and/or metal ions bound, computational structural analysis has further supported the presence and correct position of phosphate and metal-coordinating residues in all PPPs, NIFs, and PPMs, with the exception of PPM8, which shows metal coordinating residues but lacks an obvious phosphate-binding arginine or lysine.
Metal coordinated micelles based on the diblock copolymer PHEMA82-b-HQ78 PHEMA82-b-HQ78 PHEMA82-b-HQ78
The unit-cell dimensions of same metal coordinated with bpe and azp in HCl are similar.
In addition, acyclic ligands with potential metal coordinating substituents in the 4,4′-positions were prepared and complexed to copper and cobalt.
We report our study on the facile synthesis of reversible metallogels (metal coordinated polymer network) with tunable crosslinking density and metal ions, and the properties of the metallogels.
Methyltrimethoxysilane and 3-aminopropyltriethoxysilane were used as functional monomers, tetraethyl orthosilicate as cross-linker, and Al3+ as dopant to generate Lewis acid sites in the silica matrix for the metal coordinate interactions with the template dimetridazole (DMZ).
The photophysical behavior of the ligand and metal coordinated complex was characterized by steady state and time-resolved fluorescence, density functional theory calculation in combination with 1H NMR and mass spectroscopy results.
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