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This metal complex is widely used as an effective anticancer drug [104, 105].
The formation of uniform thin films of nano-crystalline metal complex is heavily dependent on several important factors.
Upon binding of F− to the boronic ester moieties, the Fe(II)/Fe(III) oxidation peak of this metal complex is shifted toward less positive potentials.
Compared with the dipolar metal complexes, all the octupolar metal complexes (including tetrahedral and octahedral complexes) have relatively large TPA cross-sections, indicating that building octupolar metal complex is an effective route to design of promising TPA material.
This reduces experimental demands because the precursor metal complex is combined with the substrate in advance, in contrast to conventional PHIP where mixing takes place during the experiment.
Metal may react with O−, S−, and N− containing ligands present in the form of OH, COOH, SH, NH2, NH, and N. A resultant metal complex is formed by coordinate bonds in which both electrons are contributed by the ligand [ 145].
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The 1 1 binding mode of the metal complex was established by combined UV vis, fluorescence, NMR and HRMS spectroscopic methods.
The metal complex was achieved by simply mixing nickel acetate, nickel nitrate, hydrazine hydrate and glycine in water.
γ-MnS crystals were formed when metal complex was used as metal source whereas Mn3O4 was the dominant product when MnSO4·H2O was used as metal source.
The structure of the metal complex was interrogated using IR, Raman, UV/Vis, NMR and XAFS, and catalytic activity was tested using an aqueous hydrogenation reaction.
The general procedure for determining the binding constant for PV by a metal complex was as follows.
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