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This work presents analytical solutions for the set of PDEs describing the bioavailability of soil metals including the kinetics of complexation for three scenarios where the metal complex in solution was fully inert, fully labile, or partially labile.
Importantly, the ability to maintain the metal complex in a highly reduced protonated state, which is essential for protection, scales with the activity for H2 oxidation, implying that future highly active catalysts, even if potentially highly oxygen sensitive, may still find technological application by exploiting this protection concept.
We believe that one possible route to this catalyst synthesis will begin by fabricating the catalytic ensemble as a discrete metal complex in a single crystal which will allow for its structure to be known by diffraction methods.
In order to prepared this type of a catalyst, a porous support is pore-size impregnated with the solution of the catalytically active species, e.g. a transition metal complex, in a solvent with low vapour pressure.
Compound 1∞[Er(LH)3(H2O)] (1), which has been structurally characterized by single-crystal X-ray crystallography, is the first binary metal/LH− complex, the first example of a succinamato(−1) metal complex in which amide coordination of LH− is realized and the first example of a polymeric LH− complex of any metal.
For an amide-linked polymer (3), the aminated poly styrene-p- aminomethyl)styrene) (co-poly styrene-p- aminomethylith a carboxylic acid derivative of the Ru metal compoly styrene-p- aminomethylouple of reagentstyrene34].
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Analogous patterns among reactions of transition metal complexes in lower oxidation states.
The dissociation of metal complexes in the soil solution can increase the availability of metals for root uptake.
In this study, we first focus on the self-assembly of magnetic metal complexes in water using diblock copolypeptides.
In addition, this approach allows to incorporate the well known properties of metal complexes in polymeric architectures.
The use and the role of non-transition metal complexes in controlled radical polymerization are also discussed.
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