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Metal cluster formation on the DNA backbone, known as so-called DNA metallization, has caught much attention for both biological and non-biological research areas.
Metal cluster compounds contain metal-metal bonds.
A metal cluster compound is one in which metal atoms are linked directly to one another (Figure 20).
Metal cluster compounds warrant a special mention here because they provide the only examples of quadruple bonds in chemistry.
Some metal cluster compounds have more than two metal atoms; an example is [Re3Cl12]3−, in which there are three rhenium atoms bonded together.
Indeed, a metal cluster can be regarded as an exceedingly tiny sample of metal, with insufficient atoms present for the molecular orbitals to form a continuous band.
The recently developed Exchange Metal Cluster Source (EXMEC) is described.
Metal cluster compounds are perspective elements of synthetic metals including superconductors.
Introducing Cu to a Co-based cluster resulted in a less oxidized metal cluster.
The metal cluster was found to form cooperatively at pH 5.4 but in a stepwise fashion at pH > 7.
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It is proposed that these findings can provide a new roadmap for the design and development of metal cluster-functionalized ILs for CO2 conversion applications.
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