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The peculiarity of such lattice hyperboloid designs consists in a minimisation of metal capacity.
The primary objective of the present work is to determine the maximum metal capacity of different catalysts that are used in different reactors of atmospheric residue desulfurization (ARDS) units by accelerated aging tests in a short duration.
The maximum metal capacity values of chromium (VI) by Nano-ZrO2-glu-CMC and Nano-ZrO2 were identified as 680 and 120 μmol g− 1, respectively in pH 1.0 2.0, while the identified maximum values of chromium (III) were 1120 and 500 μmol g− 1, respectively in pH 7.0.
It was also found that metal capacity decreases with lowering of pH.
At pH > 6.0, the metal capacity values decreased as Zn II) precipitated in the form of zincate (ZnO) and/or zinc hydroxides (Deliyanni et al. 2007).
Table 2 Comparison of adsorption capacities for the removal of different metals and dyes Adsorbents Metal Capacity (mg g−1) Dye Capacity (mg g−1) References Alumina nanoparticles Zn II) 1,047.83 CBG 263.16 Present study Multi-walled CNT – – Direct congo red 148 [28] Reactive green HE4BD 152 Golden yellow MR 141 Succinyl-grafted chitosan Zn II) 290 Cationic Dye 431 [39] Malachite NPs.
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Results of breakthrough sulfur capacity and metal dispersion of adsorbents calculated through Eqs.
For Cd II), the percentage of extraction increased from 71.39 to 98.31 % and metal capacities from 76.71 to 121.28 mg g−1 at pH range 5.0 8.0.
At pH 5.0 and 6.0, the percentage extraction values of Zn II) were 23.4 and 74.47 %, and metal capacities were 24.75 and 54.13 mg g−1.
The two mostly accepted equations to determine the amount of heavy metals capacity of adsorption onto the adsorbent used in water and wastewater treatment are Langmuir and Freundlich isotherms.
Study on bio-oil quality revealed higher content of hydrocarbon, antioxidant property, total phenolic content and metal chelating capacity.
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