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The remarkable interfacial compatibility of 0.7Li(CB11H12–0.3Li(CB11H12) with the lithium metal anode is ascribed to its high chemical stability and high physical deformability.

A dendrite-free morphology of Li metal anode is observed under the harsh condition.

A thermodynamic analysis of a solid oxide fuel cell with a liquid metal anode is developed.

Effective stabilization of lithium metal anode is the key to the development of next-generation high-energy rechargeable batteries.

The behavior of Li+ plating/stripping on the surface of lithium metal anode is greatly enhanced.

A pouch cell assembled based on the hybrid cathode and a 2× excess Li metal anode is able to simultaneously deliver a gravimetric energy density of 366 Wh kg−1 and a volumetric energy density of 581 Wh l−1.

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The interfacial resistances between the solid electrolyte and the lithium metal anode are summarized in Supplementary Table 4.

The interfacial resistance between 0.7Li(CB11H12–0.3Li(CB11H12) and the lithium metal anode was investigated using the EIS measurement with a symmetric Li/0.7Li(CB11H12–0.3Li(CB11H12)/Li cell at 25 °C (Fig. 4b).

Finally, the conclusion and future perspective of potential development on Na metal anode are proposed.

In this study, we demonstrate that the performance of the Li metal anode was significantly improved by cycling in O2-rich electrolyte.

Because the nanoparticles of tin metal are enwrapped in carbon nanofibers, the volume change and aggregation of metal anode are decreased during charging and discharging processes.

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