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The flat mercury surface was achieved by the open-circuit amalgamation of gold and it was found to display the advantageous electrochemical properties, including the high hydrogen overpotential, of mercury.
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The spectral densities of the hindered translational motions of both ions parallel and perpendicular to the Pt(100) and the liquid mercury surface are presented.
Results of various MD simulations of pure water and those with either an additional lithium or iodide ion near a Pt(100), a rigid and a liquid mercury surface are reported.
The mercury drop surface was approximately 0.52 mm.
Almost at the same time, cleavage of supercoiled DNA by DNaseI in solution and at the mercury electrode surface was investigated by ac voltammetry.
The most probable mercury species on the surface was found to be HgCl.
Elemental gold (and silver as well) is soluble in mercury, so that, when particles of the metal are brought into contact with a fresh mercury surface, they are wetted and dissolved, forming an alloy called amalgam.
Water structuring near a mercury surface has been also studied by using Metropolis Monte Carlo procedure.
The chemisorption of a single water molecule on the Cu, Ag, Au and Zn, Cd, Hg low index faces and of the (H2O n associates (n = 2−5) on Ag(111) and on a close-packed mercury surface has been investigated by CNDO method together with geometrical optimization of the atom positions.
Sensitivity analysis indicates that the dominant channel of heterogeneous mercury oxidation by HCl on Fe2O3 surface is Hg0 → FeHgCl(s) → HgCl2.
At the uncharged mercury surface, the adsorption isotherm is shown to be simple rather than mixed.
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