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Fig. 1 Workflow for extraction of melting point data.
Since melting point data are difficult to obtain without making the actual salt, predicting salt solubility remains difficult.
The products were characterized according to their 1H nuclear magnetic resonance (NMR), IR, and melting point data.
Furthermore, though odd even alternation was present in the melting point data, no mention of this feature was made by Bui [73] or explanations presented.
To obtain equilibrium melting point data, the Hoffman Weeks procedure was employed to take into account the influence of crystal morphology.
From the melting point data, it is clear that two copolyesters result when the mixtures are heated at 476 K for 6 h.
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Melting point depression data could be analysed using the full Nishi-Wang expression but additional entropy contributions to the miscibility were evident in some mixtures.
As illustrated in detail by Lin and Huang, the χ– T relationship is obtained (Fig. 5) by fitting experimental melting point depression data (Tm~ ϕ) to the following equation which is based on the Flory–Huggins theory (Eq. (5)) 30 32.
When using Eq. (5), χ is usually assumed to be constant and, because the experimentally available Tm range is narrow, this assumption holds true and melting point depression data can give a good fit to Eq. (5).
The melting point temperature data are consistent with the idea that copy number variation of the α-tryptase locus is present and accounts for most of the variation observed, although with some heterogeneity in responses we cannot exclude the possibility that multiple α-tryptase loci may exist (as with β-tryptase).
The alkaloids isolated from TAFU were determined by comparing the samples' melting point and spectral data (H-, C-NMR spectra) with those reported in literature [ 9, 11, 16].
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